![]() PRACTICE PROBLEMS : Use the electron dot structure (Lewis structure) and the electron geometry table to determine the steric number and electron geometry. What is the steric number and electron geometry of PH5? What is the steric number and electron geometry of BrF3? The valence-shell electron-pair repulsion (VSEPR) model allows us to predict which of the possible structures is actually observed in most cases. What is the steric number and electron geometry of SH2? Lewis electron structures give no information about molecular geometry, the arrangement of bonded atoms in a molecule or polyatomic ion, which is crucial to understanding the chemistry of a molecule. What is the steric number and electron geometry of SO2? ![]() Refer to the electron geometry table below.Įxamples: Use the electron geometry table to determine the steric number and electron geometry of each molecule. This means you count up the lone pairs and number of atoms attached to the central atom into one number (the steric number) and from there determine electron geometry. You also treat double and triple bonds as one group instead of 3 just like you did in molecular shape. However, with electron geometry (steric number) lone pairs and bonds are treated the same. ![]() Examples of molecules with linear geometry are carbon dioxide (CO 2 ), beryllium chloride (BeCl 2 ), and nitric oxide (NO). The atoms are arranged in a straight line, and the angle between the bonds, or bond angle, is 180 °. In molecular shape (molecular geometry) you treat the electron’s lone pairs and the bonds as two different and separate things. Linear: It specifies the geometry shaped by a central atom surrounded by two other atoms. What is the difference between electron geometry (electron domains / electron clouds / steric number) and molecular shape (molecular geometry)?īoth are very similar, but the difference is in how we treat that electron’s lone pairs versus the bonds. ![]()
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![]() ![]() Peter Pan becomes the final Disney Classic to be released on Betamax format. Disney classics were to be re-released in theatres then made available on home video for only a limited time before the next theatrical re-release 6-7 years later. Pinocchio’s price was reduced to $29.95 with buyers being made aware that no more copies would be sold after January 1986. Pinocchio, the 2nd home video released under ‘The Classics’ line. ![]() Robin Hood, being one of the less popular animated Disney movies, was released on Disney VHS tape first and prices were set high at $79.95 to cater to video rental stores and put off everyday home VHS tape buyers. The board eventually concede but with specific stipulations. Michael Eisner, Disney’s new CEO, continued to push for ‘The Classics’ home video release. He had pushed for the release of ‘the untouchables’ on VHS. These Disney animated movies were never to be released on home video, with re-releases in cinemas only. On Vacation with Mickey Mouse and Friendsĭisney select 15 animated classics including Snow White, Pinocchio and Bambi as ‘the untouchables’.Davy Crockett: King of the Wild Frontier.The First Disney VHS Films released included: Disney were worried that the strategy would harm theatrical re-releases and the 14 titles featured none of their animated classics. These titles are licensed to Fotomat for rental only. 1980 – The First Disney VHS are Releasedĭisney create their own subsidiary company ‘Walt Disney Home Video’ĭisney release 14 titles on VHS and Betamax. These were mostly mostly animated shorts. Discovision being a commercial failure, no new titles were released in this format after 1979. 11.1.1 Darren Cater The History of Disney VHS Tapes 1978-1979 – Discovisionĭisney license 6 titles to Universal for release under Discovision format. ![]() ![]() ![]() It’s actually incredibly ironic that you’re arguing that single class Occultist summoner needs more stats. In ultimate, especially, a single affix can grant you as much as +80 points to any particular stat. It was already possible to reach 10k HP on a single class character EVEN BEFORE the great +HP giveaway post-B31. This is especially important for summoners due to the sheer power for +pet bonus yellow/green affixes. Single class builds ARE viable stat-wise, you just need to realize that there are other items in the game besides blues/purples. ![]() Well, Arcanist has access to some of the best gear in the game - 4 slots Iscandra, Fateweaver`s leggins, Warpfire, immortal sage belt, that give him 30 phyz res and 25% dmg absorbtion, that might work. 2 DoT source with diferent elements - burn from Inferno and frostburn from frosen core, both mediocre at best. ![]() What Arcanist can offer? No DA, just not a single point. And 150 flat armor from Temper, and movespeed from VF. And you have up to 50% RR from mines and up to 30 flat reduction from BWC. 250 OA reduction from BWC help a lot, you can actualy hit 2.2k effective DA with Solemn watcher and no one would ever crit you. Blastshield is not much worse that miror. Demo has Firestrike and if he invest heavily in ADTCH, aka vortex soul 12%+lifegiver ring 7%+revenant 9%+ hollowed steel 5% he can facetank the whole content, excluding nasties nemesis and MQ. You can drop BWC/mines/mortar and just run around, you will stil deal dmg. Demo has a lot of cast and forget spells. ![]() Or on par, but I’d say slightly less so.Īnyhow, what’s the reference for this question? 80? End of Ultimate? What?ĭemo provide Flashbang with searing light and it work even on nemesis, cutting incoming dmg by half. Even Nightblade is less effective at surviving than you(but if you go around throwing knives…). Well, how’s this any different to Demo? With a notable difference that Demo does not have your clutch skills. I could conceive of a way, but it is not terribly original or fun. Occultist in particular is rather easy what with all those self heals, resists etcĭemolitionist…Demo is very overrated imo. Shaman and Occultist can both work as summoners(though this bores me) Nightblade COULD work, but more as a caster imo. As they would any self respecting RPG player. Unless there is an archetype that interests me that is gained via dual classing(example: Witch Hunter, Witchblade, Battlemage etc). When you find it…almost any other class will feel kinda weak tbh. You’ve got plenty of CC, you’ve got plenty of screen wide damage(if you know what you’re doing), you’ve got an “oh $%&/” button…it just takes patience to see what really works. Solo Arcanist is actually one of the most viable. Curious if anyone made solo-Occultist work around DEE? I tried and failed (miserably) with Nightblade. I myself made it work with Shaman and Soldierįrankly it’s a pain in the ass to play this way so eventually most people would respec (i know i did) but my question isn’t whether you still have the builds but rather any of you have tried them? I know JoV has a Soldier, there’s a Demo. ![]() ![]() ![]()
![]() ![]() It is available in five weights and each one has an italic version. Optimized for print, web and mobile interfaces, Open Sans has excellent legibility characteristics in its letterforms. Open Sans, designed by Steve Matteson, is one of the most widely used open source sans serif fonts. The typeface has been designed by Christian Robertson and comes in six weights and their corresponding italic styles. ![]() Introduced with Android Ice Cream Sandwich, Roboto was created specifically for the requirements of UI and high-resolution screens. Read on to find more about these free sans serif web fonts.Ĭlicking on the font name will take you to the font specimen on Google Fonts from where you can easily embed them on your website or you can download the fonts for use in your apps, games and graphic design projects. We have included a preview image for each font using their regular weight (400). All these fonts support Latin language and are available in at least 4 styles. The sans serif fonts listed below have been selected on the basis of their popularity in recent times on Google Fonts. You can also view the infographic in our earlier post to know more about serif and sans serif fonts and to understand the psychological association behind these font types. When it comes to choosing and pairing fonts, using a clean sans-serif font with a serif font is among the most popular font combinations. In this post, we have picked up some of the best free sans serif fonts available on Google Fonts that you can use in your web design projects. Sans Serif fonts are clean and minimalistic fonts that are frequently used in modern typography. ![]() ![]() ![]() But I'd say Newham is even worse than Gotham because it's in a world where people have a chance of physically and permanently transforming into their worst nightmare when they sleep-unless they take drugs to stop themselves from dreaming. I mean, the titular city of nightmares is literally called NEWHAM. You know those memes that are like "Would you live in Gotham if rent was 5 dollars a month?" That is basically this book. ![]() Tangled up in the aftermath of an explosive assassination, now Ness and the only other survivor-a Nightmare boy who Ness suspects is planning to eat her-must find their way back to Newham and uncover the sinister truth behind the attack, even as the horrors of her past loom ominously near. In order to prove herself, Ness cons her way into what’s supposed to be a simple job for the organization-only for it to blow up in her face. Ness will do anything to avoid becoming another victim, even if that means lying low among the Friends of the Restful Soul, a questionable organization that may or may not be a cult.īut being a member of maybe-cult has a price. Whether that means becoming a Nightmare that’s monstrous only in appearance, to transforming into a twisted, unrecognizable creature that terrorizes the city, no one is safe. Because in Newham, the city that never sleeps, dreaming means waking up as your worst fear. Gotham meets Strange the Dreamer in this thrilling young adult fantasy about a cowardly girl who finds herself at the center of a criminal syndicate conspiracy, in a city where crooked politicians and sinister cults reign and dreaming means waking up as your worst nightmare.Įver since her sister became a man-eating spider and slaughtered her way through town, nineteen-year-old Ness has been terrified-terrified of some other Nightmare murdering her, and terrified of ending up like her sister. ![]() ![]() This app is compatible with both iOS and Android and interacts with your smartphone’s camera. If you prefer your smartphone or tablet for photo editing, then take a closer look at Photoshop Express. #2 Way to Download Photoshop CS3 for Free: Install a Mobile App Now you can enjoy a whole week of full and free access to the entire package of functions and tools and realize all your photo manipulation ideas. Please wait a moment while your Photoshop trial is activated. ![]() Everything worked out! Now, when you download Adobe Creative Cloud on your computer, you’ll get Photoshop automatically installed as well. Find the “start free trial” button at the bottom of the page and click.Ĩ. ![]() To avoid being charged later, you must cancel your subscription before the end of the trial period. Don’t worry, you won’t be charged any money during the trial period. Next, you need to enter your payment details to activate the trial version. At this point, you will have the option to purchase an Adobe Stock subscription by paying for it separately. After selecting the appropriate one, click “Continue”.Ħ. In each of the three options, the monthly cost varies downwards in the order shown. It can be monthly billing, monthly annual billing, and one-time payment for a year. ![]() Next, you need to select a payment option. Click “Continue” when the selection is made.ĥ. If you selected individual earlier, at this point you can choose between Photoshop single app, Photography Plan, and All Apps. Based on the modality you’ve selected, you’ll see Photoshop plan options on the checkout page. Choose the suitable membership option among individual, student or teacher, or business and team. ![]() ![]() The random selector has been tested statistically through simulations so you can be assured it is doing its job of giving each name an equal chance of being picked on any particular draw from the virtual urn / bag of names. It’s like having your personal digital spin the bottle game. The visual representation of a spinning wheel adds an element of suspense and fun to the process. The RNG algorithm is cryptographically safe, results in an unbiased pick, and can be used instead of a coin, dice, or another more primitive randomizing device (which might actually be biased due to imperfect construction). Wheel pickers, also known as spinning picker wheel or random picker wheels, are digital tools that allow users to input a list of options, from which a random selection is made. This tool will randomly draw names from your class list. iPad friendly Tested to work on all modern browsers (and even some older ones too) 100 Free forever. Our software name picker first assigns incremental integer IDs to each name you enter, then uses a robust random number generator to produce a number in the range from minimum to maximum. Features: Call on your students in a different order every time. If you picked a lot of names, don't forget that you can easily select them all (Cltr+A on a PC) and them copy and paste as you wish. ![]() The maximum names the name picker can pick for you in one go is 1,000. ![]() The wheel then spins and gradually slows down, eventually stopping at the chosen option. Whether youre struggling to decide who should go first in a game, which restaurant to visit, or need a creative way to pick a student for a classroom activity, simply input names or words and let the wheel decide. When you spin the wheel, the random number generator selects a number corresponding to one of the options on the wheel. Spin The Wheel is an interactive, easy to use web tool designed to make decision making fun. Then simply press the 'Pick a Random Name' button and let our randomizer do its job. Our random name picker can handle up to 10,000 names. Copy/paste from a spreadsheet works very well. You start in similar fashion to how you would draw one random name from a list, but you need to change the default value of the "Number of names to pick" field from 1 to as many as you'd like to select from the provided list. This is a function that produces a sequence of numbers that lack any pattern, i.e., appear random. To generate a single random name, start by feeding the tool with a list of names, one name per row (where 'one name' can consist of first and last name, etc.). It's work is equivalent to rolling a dice with as many sides as there are names - each one has an equal probability to be picked. Then simply press the "Pick a Random Name" button and let our randomizer do its job. ![]() To generate a single random name, start by feeding the tool with a list of names, one name per row (where "one name" can consist of first and last name, etc.). ![]() ![]() ![]() Beatport Link and Beatsource Link is accessible with all 3 offered subscriptions. *Please note: An Internet connection and a TIidal Premium or HiFi subscription, Soundcloud Go+ subscription is required.Lightning-Connection cable, USB cable, OTG cable (Android), power supply Turntable spindle cavity for easy positioning on turntables.Search mode for fast search within tracks.Signal meter LED chain selectable for master & PFL.Play, cue, sync and auto loop controls (double / half).It works well as an IOS DJ controller for an iPad of any size. It will hold an iPad Pro that is as big as 12.9 inches, and it uses the Algoriddim’s djay Pro software for both IOS and Android. This is a four channel DJ controller that supports IOS and Android devices. Set, access and delete 8 hot cue points on 2 decks Reloop Mixon 4 Serato DJ / djay Pro DJ Controller.MIDI-compatible: mappings available for Virtual DJ & Traktor.Real-time vocal and instrumental isolation with djay Pro AI Neural Mix™**.Mix millions of tracks instantly with djay and the popular streaming services Tidal*, Soundcloud Go+*, Beatport Link* and Beatsource Link*.Large navigation encoder with load buttons.Sturdy & flat build with 45-mm Pro faders.Integrated, low-latency 4-channel audio interface for iOS, Android & USB connectivity.Dual FX Mode: control FX and filter simultaneously.Dedicated bi-polar LFP/HPF sound filter control.Powerful, colour-coded, rubberised trigger section for transport & cue mode per deck.Connect them all: iOS / Android / Mac / PC.Designed for award winning djay (iOS/Android) and djay for Mac by Algoriddim.This means you can work on your playlists, cues and so on wherever you like, syncing to other devices as you please. Ultra-portable, yet sturdy all-in-one DJ controller with audio interface The idea behind Mixo is that you have a single, central cloud library for all your DJ music, that you can access on Mac, Windows, Android, iOS, even Linux, to stream your music anywhere.Remember we will try to beat or match the price of any other genuine UK dealer. There’s currently no support for DJing with Amazon Music there. At the moment djay only supports Tidal and Soundcloud on their Windows desktop DJ software and their Android App. Looking for the best DJ & Producer gear in the North? Come and visit us at our Bradford City Centre store and demo the equipment we have. The iPad version of Traktor’s free DJ software does support SoundCloud Go+ so its worth taking a look a that subscription service to see if it suits your needs. Need any help? Call us on 01274 394 730 or e-mail No other hardware offers such versatile support, and inside the box with the BeatPad 2 are USB, Apple Lightning and Android OTG cables. Whether you're using DJAY 2 on your iOS or Android device, or using DJAY Pro on Mac – the integration is seamless and completely stress-free. Based on the original BeatPad controller, which quickly established itself as an affordable yet professional DJ tool for „Smart-Device DJs“, the BeatPad 2 works plug-and-play across all platforms. They can then vote for their favourite tracks which you can view in real time, allowing you to hone your playlist to please your audience!įinally the Beatpad 2 from Reloop. THE professional and truly reliable cross-platform controller that is able to completely utilize the full potential of the award-winning DJAY 2 mixing software from Algoriddim. With the fantastic DJUCED app, you can share your playlist with your guests. New from Hercules is the Universal DJ Controller. Enables you to be as creative as a pro DJ and enjoy freedom to move and groove with your party, whilst mixing from your smartphone or tablet thanks to the built-in Bluetooth and wireless technology. Also available in a white finish & comes with the full version of rekordbox DJ software. Just plug in your laptop, tablet or smartphone and start to play. And use the sampler, Hot Cues and Pad FX inherited from professional hardware to bring more creativity to your sets. Next the WeGO4 from Pioneer DJ. Mix seamlessly with tactile controls and jog wheels for scratching. Shop for Native Instruments Traktor S2 MK2 here. Comes with the full version of Traktor Pro DJ software. Easily access all essential Traktor features in a compact, focused format. Rugged and portable, ideal for new or seasoned DJs. Fine-tuned for maximum Traktor software integration, the S2 MK2 also pairs with Traktor DJ for iPad and iPhone as the cornerstone of your mobile DJ setup. A quick guide to some of the best DJ controllers with iOS and/or Android connection capability.įirst up from N ative Instruments the Traktor Kontrol S2 MK2. Compact, mobile, and intuitive – the essential 2-deck professional DJ controller for Traktor. ![]() ![]() ![]() JetBrains PhpStorm 2018.2.6 Crack Full License Key With. Now,PhpStorm is available for individual. Phpstorm activation code: Hello i am back with a super cool info about JetBrains Php Storm. PhpStorm 2018.2.3 Crack + Keygen With License Key Full Download Here PhpStorm Crack v2018.2.3 is the fresh version of PHP language. PhpStorm 2018.2 License Keygen Features: Clever PHP editor. JetBrains PhpStorm 2018 Crack With License Server is Here. WebStorm Crack is web developing application allows an individual to correct all kind of syntax mistakes within virtually no time. PhpStorm 2018 Keygen is an IDE (integrated advancement. PhpStorm 2018.2.5 Crack allows IntelliJ IDEA to enable developers to write code. 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